The separation of substances during distillation depends primarily on the differences in their boiling points, or more specifically, their volatilities.
The volatility of a substance is a measure of how easily it turns into a gas (vaporizes) when heated.
When a person stands near a fire, they feel hot primarily through radiation and convection.
Radiation
This is the transfer of heat through electromagnetic waves, primarily infrared radiation, and does not require a medium (like air or water) to travel.
Fire radiates energy in all directions, which is why you can feel the warmth even if the air around you is cold.
When the radiant energy from the fire hits your skin, it is absorbed and converted into thermal energy, making you feel warm.
Convection
This is the transfer of heat through the movement of a heated fluid (in this case, air).
The air directly above the fire gets hot, becomes less dense, and rises.
This creates air currents that carry heat upward and can warm a person standing nearby.
However, when standing to the side of a fire, the effect of convection is usually much less than radiation, as the hottest air rises and billows away from you.