The functional group for a ketone is a carbonyl group (C=O), where the carbonyl carbon is bonded to two other carbon atoms.
The general formula for a ketone is R–C(=O)–R' or CnH2nO;
Where the central carbon atom is double-bonded to an oxygen atom and single-bonded to two alkyl or aryl groups (R and R'). The simplest ketone is propanone (acetone), with the formula C₃H₆O.
Complete oxidation of methane (CH₄) in the presence of oxygen produces carbon dioxide (CO₂) and water (H₂O) with the release of energy (combustion reaction):
The oxidation of a tertiary alcohol generally gives no reaction under normal conditions
No alpha hydrogen:
The carbon bonded to the -OH group (the alpha-carbon) in a tertiary alcohol has no hydrogen atoms attached to it, as it is already bonded to three other carbon groups.
Mechanism requires an alpha hydrogen:
Standard oxidation reactions of alcohols involve the removal of a hydrogen atom from the alpha-carbon and the formation of a C=O double bond.
Carbon-carbon bond breakage:
To oxidize a tertiary alcohol, a C-C bond would need to be broken, which requires much harsher conditions than those used for primary or secondary alcohols.
The theory that free radicals cause cellular damage is known as the free radical theory.
Most notably, the free radical theory of aging posits that age-related damage originates from oxidative stress induced by these molecules.
Proposed by Denham Harman in 1956,
This theory suggests that free radicals, which are unstable atoms or molecules with unpaired electrons, damage DNA, proteins, and other cellular components, leading to aging and disease over time.