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Sticky Note
Oxidation of a tertiary alcohol generally gives?
  1. Carboxylic acid
  2. No reaction
  3. Aldehyde
  4. Ketone
Explanation

The oxidation of a tertiary alcohol generally gives no reaction under normal conditions 

No alpha hydrogen:

The carbon bonded to the -OH group (the alpha-carbon) in a tertiary alcohol has no hydrogen atoms attached to it, as it is already bonded to three other carbon groups. 

Mechanism requires an alpha hydrogen:

Standard oxidation reactions of alcohols involve the removal of a hydrogen atom from the alpha-carbon and the formation of a C=O double bond. 

Carbon-carbon bond breakage:

To oxidize a tertiary alcohol, a C-C bond would need to be broken, which requires much harsher conditions than those used for primary or secondary alcohols. 

Related MCQs

  1. Temporary water connections
  2. Underground and permanent water-supply lines
  3. High-temperature steam lines
  4. Drainage of rainwater only
اس سوال کو وضاحت کے ساتھ پڑھیں

  1. 10–20 minutes
  2. 30–60 minutes
  3. 2–4 hours
  4. 12–24 hours
اس سوال کو وضاحت کے ساتھ پڑھیں

  1. Vertical drop fall
  2. Glacis fall
  3. Montague type fall
  4. Inglis fall
اس سوال کو وضاحت کے ساتھ پڑھیں

آکسیجن زیادہ تر عناصر کے ساتھ عمل کرکے دو عنصری مرکبات بناتی ہے جنہیں کیا کہتے ہیں؟
  1. Bases
  2. Oxides
  3. Acids
  4. None of these
اس سوال کو وضاحت کے ساتھ پڑھیں

پانی اور کاربن ڈائی آکسائڈ کے سالمے مل کر کیا بناتے ہیں؟
  1. Nitric acid
  2. Carbonic acid
  3. Sulfuric acid
  4. None of these
اس سوال کو وضاحت کے ساتھ پڑھیں

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